Characteristics and uses of OPP
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- Time of issue:2021-07-13
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(Summary description)Characteristics
Ortho-phenylphenol, a white flake crystal, is an important new fine chemical product and organic intermediate. It is widely used in sterilization, anti-corrosion, printing and dyeing auxiliaries and surfactants, as well as stabilizers for the synthesis of new plastics, resins and polymer materials. Its specific uses are as follows:
Antiseptic and antiseptic
Because o-phenylphenol and its sodium salt have high herbicidal activity, broad-spectrum bactericidal and mildew-removing capabilities, and are non-toxic and tasteless, they are good preservatives and can be used for anti-mildew and fresh-keeping of fruits and vegetables, especially for Anti-mold citrus, can also be used to treat lemons, pineapples, melons, fruits, pears, peaches, tomatoes and cucumbers, etc., to minimize decay.
Dyeing vector
Ortho-phenylphenol and its water-soluble sodium salt can be used as a dye carrier for polyester fibers, and can also be used as a carrier when dyeing hydrophobic synthetic fibers such as chlorinated fiber and polyester.
Flame retardant material
When the polymer material containing organic phosphorus compounds is burned, a graphite-like carbonized film will be formed on the surface of the material to isolate the polymer from the air. It has good flame-retardant properties, high flame-retardant efficiency, low volatility, oil and hydrolysis resistance It has good performance and is more and more widely used, and will gradually replace the inorganic and halogen-containing flame-retardant materials used today. Using o-phenylphenol as a raw material, a new type of phosphorus-containing flame-retardant intermediate DOPO can be synthesized, mainly for the following applications:
(1) Flame retardant polyester
DOP0 is a raw material that reacts with itaconic acid to produce intermediate ODOP-BDA, which can partially replace ethylene glycol to obtain a new type of phosphorus-containing flame-retardant polyester. Studies have shown that when the phosphorus content in PET and PEN reaches 0.75% and 0.5%, respectively, polyester exhibits a good flame-retardant effect. The world's annual production of polyester has reached more than 30 million tons. If 5% of it is phosphorus-containing flame-retardant polyester, more than 50,000 t/a of o-phenylphenol is required.
(2) Epoxy resin
Epoxy resin has excellent bonding properties, electrical insulation properties and other advantages. It is widely used in adhesives, electronic instruments, aerospace, coatings and advanced composite materials. In 2004, the consumption of epoxy resin in the world reached more than 200,000 tons. /year. DOPO reacts with benzoquinone to form ODOPB, which partially replaces bisphenol A and forms a new flame-retardant epoxy resin. Studies have shown that the newly synthesized phosphorus-containing flame-retardant epoxy resin has a better flame-retardant effect than the Br flame-retardant epoxy resin containing 17.26% when the P content is 2.1%, and does not produce smoke, and has excellent thermal stability. For epoxy resin without added flame retardant.
(3) Organic dissolution
Using DOPO as raw material, the synthesis of 2DOPO-A partially replaces the synthetic polyamide monomer DABP. The resulting new polyamide is soluble in solvents such as NMP, DMAc, DMF and DMSO. At the same time, it has thermal stability and flame retardancy at high temperatures. Sex has also improved significantly.
(4) Antioxidant
The Taiwan patent reported the use of DOPO to synthesize phosphorus-containing antioxidants, antioxidants for unsaturated polyesters, phenols and greases, and Formosa Plastics Group for copper-based sheets for computers, and it has good thermal stability.
(5) Stabilizer
The Japanese patent reported the stabilizer of polymer materials synthesized by DOPO. Adding this compound during the processing of polyethylene, polypropylene, and polyvinyl chloride can improve the stability of polymer compounds during thermal processing.
(6) Luminous matrix
Organic light-emitting diodes are important optoelectronic materials. Sun et al. used DOPO derivatives as monomers to synthesize polymers with light-emitting properties. DOPO derivatives act as emission groups and can emit blue light with a wavelength of 325-350nm, which can be applied to Organic light-emitting diodes.
Agglomerate
Phenolic resin has the advantages of high mechanical strength, good electrical insulation performance, excellent heat resistance, and flame retardancy. It is widely used in the preparation of glass fiber reinforced plastics, molding compounds, coatings, adhesives, etc. However, phenolic resins also have disadvantages, such as heat resistance. Poor performance, etc. Replace phenol with o-phenylphenol to synthesize a new phenolic resin, which has high thermal stability and low water absorption.
New drugs
According to related reports, o-phenylphenol is used to synthesize cholesteryl ester hydrolysis inhibitors, antispasmodic drugs, anti-inflammatory drugs and analgesics,
Characteristics and uses of OPP
(Summary description)Characteristics
Ortho-phenylphenol, a white flake crystal, is an important new fine chemical product and organic intermediate. It is widely used in sterilization, anti-corrosion, printing and dyeing auxiliaries and surfactants, as well as stabilizers for the synthesis of new plastics, resins and polymer materials. Its specific uses are as follows:
Antiseptic and antiseptic
Because o-phenylphenol and its sodium salt have high herbicidal activity, broad-spectrum bactericidal and mildew-removing capabilities, and are non-toxic and tasteless, they are good preservatives and can be used for anti-mildew and fresh-keeping of fruits and vegetables, especially for Anti-mold citrus, can also be used to treat lemons, pineapples, melons, fruits, pears, peaches, tomatoes and cucumbers, etc., to minimize decay.
Dyeing vector
Ortho-phenylphenol and its water-soluble sodium salt can be used as a dye carrier for polyester fibers, and can also be used as a carrier when dyeing hydrophobic synthetic fibers such as chlorinated fiber and polyester.
Flame retardant material
When the polymer material containing organic phosphorus compounds is burned, a graphite-like carbonized film will be formed on the surface of the material to isolate the polymer from the air. It has good flame-retardant properties, high flame-retardant efficiency, low volatility, oil and hydrolysis resistance It has good performance and is more and more widely used, and will gradually replace the inorganic and halogen-containing flame-retardant materials used today. Using o-phenylphenol as a raw material, a new type of phosphorus-containing flame-retardant intermediate DOPO can be synthesized, mainly for the following applications:
(1) Flame retardant polyester
DOP0 is a raw material that reacts with itaconic acid to produce intermediate ODOP-BDA, which can partially replace ethylene glycol to obtain a new type of phosphorus-containing flame-retardant polyester. Studies have shown that when the phosphorus content in PET and PEN reaches 0.75% and 0.5%, respectively, polyester exhibits a good flame-retardant effect. The world's annual production of polyester has reached more than 30 million tons. If 5% of it is phosphorus-containing flame-retardant polyester, more than 50,000 t/a of o-phenylphenol is required.
(2) Epoxy resin
Epoxy resin has excellent bonding properties, electrical insulation properties and other advantages. It is widely used in adhesives, electronic instruments, aerospace, coatings and advanced composite materials. In 2004, the consumption of epoxy resin in the world reached more than 200,000 tons. /year. DOPO reacts with benzoquinone to form ODOPB, which partially replaces bisphenol A and forms a new flame-retardant epoxy resin. Studies have shown that the newly synthesized phosphorus-containing flame-retardant epoxy resin has a better flame-retardant effect than the Br flame-retardant epoxy resin containing 17.26% when the P content is 2.1%, and does not produce smoke, and has excellent thermal stability. For epoxy resin without added flame retardant.
(3) Organic dissolution
Using DOPO as raw material, the synthesis of 2DOPO-A partially replaces the synthetic polyamide monomer DABP. The resulting new polyamide is soluble in solvents such as NMP, DMAc, DMF and DMSO. At the same time, it has thermal stability and flame retardancy at high temperatures. Sex has also improved significantly.
(4) Antioxidant
The Taiwan patent reported the use of DOPO to synthesize phosphorus-containing antioxidants, antioxidants for unsaturated polyesters, phenols and greases, and Formosa Plastics Group for copper-based sheets for computers, and it has good thermal stability.
(5) Stabilizer
The Japanese patent reported the stabilizer of polymer materials synthesized by DOPO. Adding this compound during the processing of polyethylene, polypropylene, and polyvinyl chloride can improve the stability of polymer compounds during thermal processing.
(6) Luminous matrix
Organic light-emitting diodes are important optoelectronic materials. Sun et al. used DOPO derivatives as monomers to synthesize polymers with light-emitting properties. DOPO derivatives act as emission groups and can emit blue light with a wavelength of 325-350nm, which can be applied to Organic light-emitting diodes.
Agglomerate
Phenolic resin has the advantages of high mechanical strength, good electrical insulation performance, excellent heat resistance, and flame retardancy. It is widely used in the preparation of glass fiber reinforced plastics, molding compounds, coatings, adhesives, etc. However, phenolic resins also have disadvantages, such as heat resistance. Poor performance, etc. Replace phenol with o-phenylphenol to synthesize a new phenolic resin, which has high thermal stability and low water absorption.
New drugs
According to related reports, o-phenylphenol is used to synthesize cholesteryl ester hydrolysis inhibitors, antispasmodic drugs, anti-inflammatory drugs and analgesics,
- Categories:Industry News
- Author:
- Origin:
- Time of issue:2021-07-13
- Views:0
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